For mattresses you must saturate the spot throughly to get deep down into the padding and springs to neutralize the urine. If the cat has urinated alot in one spot, the mattress can be soiled all the way to the other side! Let the area dry for 24-48 hours without bedding then reapply if necessary.
For sofas the same directions as above apply but always check for color-fastness in a hidden area before using. Cotton is used in alot of upholstery fabrics and is easily bleached. If your sofa pillow cushion covers can be unzipped and taken off (must be color-fast and washable) you can put them in the washing machine. See How to Remove from Clothing, Comforters and Bedding for instructions.
For Leather Sofas see How to Remove from Leather.
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